Short free-response question
Ionization energies across period 3
- Unit 1
- 4 points
- About 9 minutes
You can use a calculator on this question, just like on exam day.
A shorter multipart question that sticks to one or two topics. Each part usually asks for one calculation, claim or explanation. On the exam: 4 questions (Questions 4–7), part of the 1-hour-45-minute free-response section; calculator allowed.
The question and its sources
The table gives ionization energies of three elements in period 3.
Table 1. Ionization energies
| Element | First ionization energy (kJ/mol) | Second ionization energy (kJ/mol) |
|---|---|---|
| Na | 496 | 4562 |
| Mg | 738 | 1451 |
| Al | 578 | 1817 |
Source: Standard reference values, rounded
Suggested time: 9 minutes
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Part (a)
1 pointExplain why the first ionization energy of Mg is greater than that of Na. Use Coulomb's law and principles of atomic structure.
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Part (b)
1 pointExplain why the first ionization energy of Al is less than that of Mg, even though Al has a greater nuclear charge.
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Part (c)
1 pointIs the radius of an Mg²⁺ ion greater than, less than, or equal to the radius of an Mg atom? Justify your answer.
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Part (d)
1 pointThe second ionization energy of Na is much greater than the second ionization energy of Mg, even though Mg has the greater nuclear charge. Explain this difference using principles of atomic structure.
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